Why entropy is extensive, partial molar quantity is intensive property and Gibbs-Duhem equation was deduced. 偏摩尔量是强度性质以及吉布斯&杜亥姆(Gibbs一Duhem)公式的推导等等。
Study on the Gibbs-Duhem Equation Used on the Thermodynamic Stability of Polymer System Gibbs-Duhem公式用于高聚物热力学稳定性研究
Integration of Gibbs-Duhem Equation and its Application in Liquid-Vapor Equilibrium Gibbs-Duhem方程与前传网的集成方法及其在汽液相平衡中的应用
The basic differential equations are derived from Gibbs-Duhem equation and can be solved easily by iterative method. 基本微分方程由Gibbs-Duhem式导得,能方便地利用迭代法求解。
The results show that this model may be respectively reduced to the Flory-Huggins equation, the Wilson equation and NRTL equation in solution thermodynamics under some special conditions, and it can be verified by the Gibbs-Duhem equation, and expresses the thermodynamic properties of partially miscible systems. 结果表明:该模型在某些特殊条件下,可分别还原为溶液热力学的Flory-Huggins方程、Wilson方程和NRTL方程,并且能够满足Gibbs-Duhem方程,能够描述部分互溶体系的热力学性质。
Application of the θ function to the modified Gibbs-Duhem equation θ函数在变通的Gibbs-Duhem关系式中的应用
In the light of estimation model for ternary excess properties, an approximate analytical procedure for ternary Gibbs-Duhem equation was proposed, and verification by previous ternary systems as Cd-Bi-Pb and Zn-In-Cd was also made. 本文借助三元过剩性质的估算模型,得到一种三元Gibbs-Duhem方程的近似解析法,并在Cd-Bi-Pb和Zn-In-Cd两个三元系中做了验证。
Complete integration of Gibbs-Duhem equation along phase boundaries in multicomponent systems 多元系相界上Gibbs-Duhem方程的完整积分
The activity coefficient of carbon in Fe-C-Si ternary melt and its related activity interaction coefficients were calculated by the Gibbs-Duhem equation integration. 用Gibbs-Duhem方程积分计算了Fe-C-Si三元熔体的碳的活度系数lnγC。